OK, here goes.
Probably one of the most painful, scary ways to die is by high levels of carbon dioxide. It induces panic and fear, and a huge range of physiological distress symptoms. Yes, it can be fairly quick. But every mammal and bird’s respiratory system is basically ready to trigger a huge number of endocrine and neurochemical cascades to get you the hell out of there if you start breathing too much CO2. That’s because of evolution…we are evolved to get out of high-CO2 environments.
On the other hand, helium is not present in our natural environment in more than trace amounts. In particle accelerators and other places cooled with liquid helium, you have to constantly wear a sensor on top of your hat (since helium rises) that tells you if a helium leak has started. If one starts and you don’t have a sensor, you won’t know until you pass out and possibly die. No panic or physiological distress, you just get a bit giggly and then fall over, and suddenly you’re talking to St. Peter.
I know that it’s seen as the humane gold standard to use CO2 for killing rats and mice and baby chicks and quails, but why? It seems horrible.
Helium tanks are available from any party store etc., they’re not hard to obtain. I’ve previously made helium chambers to humanely dispatch of pet rodents suffering from cancer or other untreatable ailments. It was always a little sweet, because these old, very ill animals would have about 3-5 seconds of acting “happy,” much like their younger selves for a brief flash, and then they were just gone. No frantic running around or squeaking in terror. It looked genuinely peaceful.
It is not difficult to build a helium chamber for these purposes, and can be done for a few dollars, but it does take a little thought and consideration (it doesn’t work the same as CO2 because helium rises and is very light). If anyone wants a rough sketch of the plan for the helium chamber I have built and used, I’m happy to provide.